A NOVEL SYNTHETIC PROCEDURE OF VINYLACETAMIDE AND ITS FREE-RADICAL POLYMERIZATION

被引：62

作者：

AKASHI, M ^{[1
]}

YASHIMA, E ^{[1
]}

YAMASHITA, T ^{[1
]}

MIYAUCHI, N ^{[1
]}

SUGITA, S ^{[1
]}

MARUMO, K ^{[1
]}

机构：

[1] SHOWA DENKO LTD,OITA RES LAB,OITA 87001,JAPAN

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1990年 / 28卷 / 12期

关键词：

D O I：

10.1002/pola.1990.080281224

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The pyrolysis of N‐(α‐methoxyethyl) acetamide, which was obtained by one‐step reaction of acetamide, acetaldehyde, and methanol, gave N‐vinylacetamide (NVA) in a good yield. The polymerizability and copolymerizability of NVA were studied. Free radical polymerization was carried out in the presence of radical initiator or by γ‐ray irradiation. The monomer reactivity ratios of NVA were estimated in the copolymerization with acrylamide, vinyl acetate, and methyl methacrylate. The solvents were found to influence the monomer reactivity ratio. NVA showed a typical copolymerizability as nonconjugated vinyl monomer, and Q and e values were obtained in DMF as 0.16 and −1.57, respectively. Copyright © 1990 John Wiley & Sons, Inc.

引用

页码：3487 / 3497

页数：11

共 15 条

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