LADDER POLYMERS - THE NEW GENERATION

被引：166

作者：

SCHLUTER, AD ^{[1
]}

机构：

[1] MAX PLANCK INST POLYMER RES,W-6500 MAINZ,GERMANY

来源：

ADVANCED MATERIALS | 1991年 / 3卷 / 06期

关键词：

DIELS-ALDER POLYMERIZATION; SOLUBILITY EFFECTS; MOLECULAR STRUCTURE; GRAPHITIC RIBBONS;

D O I：

10.1002/adma.19910030603

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polymers with high thermal, mechanical, and chemical stability based on a ladder-type structure (see figure), have suffered in the past from insolubility or infusibility. A new strategy for the controlled synthesis of processible ladder polymers, based on Diels-Alder polymerization is reviewed, and the polymers considered as precursors to graphite ribbons, materials predicted to have properties lying between graphite and single-stranded polyacetylene.

引用

页码：282 / 291

页数：10