CATALYTIC PROCEDURE FOR THE SYNTHESIS OF CYCLOALKANEMETHANOLS FROM CYCLOALKENES AND AQUEOUS METHYL FORMATE

被引：19

作者：

JENNER, G

机构：

[1] Laboratoire de Piézochimie Organique (associé au CNRS), EHICS, Université Louis Pasteur, 67008 Strasbourg, 1, rue Blaise Pascal

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 04期

关键词：

D O I：

10.1016/S0040-4039(00)79480-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cycloalkanemethanols are synthesized via hydrocarbonylation (hydroformylation) of the corresponding cycloalkenes in the presence of aqueous methyl formate. Methyl formate is the source of carbon monoxide and hydrogen is generated by the water gas shift reaction. The selectivity is affected by the concomitant hydrogenation process.

引用

页码：505 / 508

页数：4

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