HORSE RADISH PEROXIDASE-CATALYZED OXIDATIVE COUPLING OF METHYL SINAPATE TO GIVE DIASTEREOISOMERIC SPIRO DIMERS

被引：17

作者：

SETALA, H ^{[1
]}

PAJUNEN, A ^{[1
]}

KILPELAINEN, I ^{[1
]}

BRUNOW, G ^{[1
]}

机构：

[1] UNIV HELSINKI,DEPT CHEM,SF-00014 HELSINKI,FINLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1994年 / 09期

关键词：

D O I：

10.1039/p19940001163

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The oxidative coupling of methyl sinapate with H2O2/horse radish peroxidase at pH 4 in the presence of methanol gives dimeric spiro structures of a novel type. The crystal structures of two diastereoisomers have been determined. The coupling reaction shows some three selectivity.

引用

页码：1163 / 1165

页数：3