THE SPECTRUM OF PHOTOEXCITED ND-3+ IONS IN LACL3

被引：12

作者：

PELLETIERALLARD, N ^{[1
]}

PELLETIER, R ^{[1
]}

SHERTZER, J ^{[1
]}

机构：

[1] COLL HOLY CROSS,DEPT PHYS,WORCESTER,MA 01610

来源：

JOURNAL OF CHEMICAL PHYSICS | 1990年 / 93卷 / 01期

关键词：

D O I：

10.1063/1.459614

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nine new levels of the 4f3 configuration of trivalent neodymium in lanthanum chloride have been identified through absorption experiments on the photoexcited ions. Transitions from the ground state to the μ=5/2 levels are forbidden by the selection rules; by populating the metastable levels (μ=1/2 and 3/2), absorption transitions to the μ=5/2 levels are observed. A least squares fit has been carried out for the 127 known levels of Nd 3+:LaCl3 using a Hamiltonian with 20 adjustable parameters. © 1990 American Institute of Physics.

引用

页码：14 / 17

页数：4

共 9 条

[1] ELECTRON PARAMAGNETIC RESONANCE OF PHOTOEXCITED STATES OF ND+3 IN SINGLE CRYSTALS OF LACL3 [J].

CLARKE, RH ;

HUTCHISON, CA .

PHYSICAL REVIEW LETTERS, 1971, 27 (10) :638-+

[2] MAGNETIC-RESONANCE INVESTIGATIONS OF INFRARED LEVELS OF PHOTOEXCITED ND+3 IN LACL3 [J].

CLARKE, RH ;

CONNORS, RE .

PHYSICS LETTERS A, 1974, A 47 (04) :273-274

[3] ELECTRON-PARAMAGNETIC RESONANCE OF PHOTO-EXCITED ND-144(3+) ION-PAIRS IN LACL3 SINGLE-CRYSTALS [J].

CLEMENS, JM ;

HUTCHISON, CA .

PHYSICAL REVIEW B, 1983, 28 (01) :50-66

[4] SPECTRUM OF ND-3+-LACL-3 [J].

CROSSWHITE, HM ;

CROSSWHITE, H ;

KASETA, FW ;

SARUP, R .

JOURNAL OF CHEMICAL PHYSICS, 1976, 64 (05) :1981-1985

[5] RARE-EARTH INFRARED LIFETIMES AND EXCITON MIGRATION RATES IN TRICHLORIDE CRYSTALS [J].

GANDRUD, WB ;

MOOS, HW .

JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (05) :2170-+

[6] ELECTRON-PARAMAGNETIC RESONANCE OF PHOTOEXCITED TRIVALENT NEODYMIUM IONS IN LANTHANUM TRICHLORIDE SINGLE-CRYSTALS [J].

HESSLER, JP ;

HUTCHISON, CA .

PHYSICAL REVIEW B, 1973, 8 (05) :1822-1826

[7] 2-PHOTON EXCITATION OF PHOTOEXCITED ND-3+ COUPLED IONS IN LACL3 CRYSTALS [J].

PELLETIERALLARD, N ;

PELLETIER, R .

JOURNAL OF LUMINESCENCE, 1990, 46 (04) :217-226

[8]

PELLETIERALLARD N, 1987, REV SCI INSTRUM, V55, P4425

[9]

RANA RS, 1982, J CHEM PHYS, V77, P4400, DOI 10.1063/1.444441

← 1 →