STEREOSPECIFIC SYNTHESIS OF (25R)-26-HYDROXYCHOLESTEROL VIA [2,3] SIGMATROPIC REARRANGEMENT - A NEW STEREOSELECTIVE 2-CARBON HOMOLOGATION OF 20-KETO STEROIDS TO THE 23-ALDEHYDE

被引：25

作者：

MIDLAND, MM

KWON, YC

机构：

来源：

TETRAHEDRON LETTERS | 1985年 / 26卷 / 41期

关键词：

D O I：

10.1016/S0040-4039(01)80842-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

引用

页码：5021 / 5024

页数：4

共 18 条

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PAI, GG .

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[4] ON THE C-25 CHIRALITY OF 26-HYDROXYCHOLESTEROL [J].

BYON, CY ;

GUT, M ;

TOOME, V .

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[5]

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[6]

JAVITT NB, 1981, J BIOL CHEM, V256, P2644

[7] BIOLOGICAL-ACTIVITY OF SOME OXYGENATED STEROLS [J].

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CHEN, HW ;

HEINIGER, HJ .

SCIENCE, 1978, 201 (4355) :498-501

[8] SYNTHESIS OF (20R,25R)-CHOLEST-5-ENE-3-BETA,26-DIOL AND THE OCCURRENCE OF BASE-CATALYZED 1,5-HYDRIDE SHIFT IN A STEROIDAL 1,5-KETOL [J].

KLUGE, AF ;

MADDOX, ML ;

PARTRIDGE, LG .

JOURNAL OF ORGANIC CHEMISTRY, 1985, 50 (13) :2359-2365

[9] STEREOSPECIFIC SYNTHESIS OF HYDROXYLATED STEROID SIDE-CHAINS - SYNTHESIS OF 25,28-DIHYDROXY-7,8-DIHYDROERGOSTEROL AND ITS C-24 EPIMER VIA [2,3] SIGMATROPIC REARRANGEMENT [J].

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TETRAHEDRON LETTERS, 1985, 26 (41) :5017-5020

[10]

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