B-CHLORODIISO-2-ETHYLAPOPINOCAMPHEYLBORANE - AN EXTREMELY EFFICIENT CHIRAL REDUCING AGENT FOR THE REDUCTION OF PROCHIRAL KETONES OF INTERMEDIATE STERIC REQUIREMENTS

被引:27
作者
BROWN, HC
RAMACHANDRAN, PV
TEODOROVIC, AV
SWAMINATHAN, S
机构
[1] Herbert C. Brown and R. B. Wetherill Laboratories of Chemistry, Purdue University, West Lafayette
关键词
D O I
10.1016/S0040-4039(00)93576-7
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
B-Chlorodiiso-2-ethylapopinocampheylborane, Eap2BCl, prepared from 2-ethylapopinene and chloroborane-methyl sulfide reduces prochiral ketones of intermediate steric requirements to the product alcohols in very high ee.
引用
收藏
页码:6691 / 6694
页数:4
相关论文
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