AN IMPROVED METHOD FOR THE SYNTHESIS OF CATIONIC (ETA(5)-CYCLOPENTADIENYL) (ETA(3)-ALLYL)MO(CO)(NO) COMPLEXES - THE BENEFIT OF 1,2-DIMETHOXYETHANE AS A SOLVENT

被引：28

作者：

COSFORD, NDP ^{[1
]}

LIEBESKIND, LS ^{[1
]}

机构：

[1] EMORY UNIV,DEPT CHEM,ATLANTA,GA 30322

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 04期

关键词：

D O I：

10.1021/om00016a059

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In contrast to suggestions in the literature that ether solvents are incompatible with nitrosonium salts, treatment of (eta3-allyl)(eta5-cyclopentadienyl)dicarbonylmolybdenum complexes with solid NOPF6 in 1,2-dimethoxyethane at -10-degrees-C produces analytically pure [(eta3-allyl)carbonyl(eta5-cyclopentadienyl)nitrosylmolybdenum][PF6] as yellow solids.

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页码：1498 / 1503

页数：6

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