STUDIES ON TRANSITION-METAL PARACYCLOPHANE COMPOUNDS - REACTIONS OF [(M(ETA(6)-C16H16)CL-2)(2)] (M=RU, OS) WITH TERTIARY PHOSPHINES - THE CRYSTAL-STRUCTURES OF [RU(ETA(6)-C16H16)CL-2(PPH(3))].CHCL3 AND [RU(ETA(6)-C6H6)CL-2(PPH(3))].2CH(2)CL(2)

被引：36

作者：

ELSEGOOD, MRJ

TOCHER, DA

机构：

[1] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

[2] UNIV LONDON UNIV COLL,DEPT CHEM,LONDON WC1H 0AJ,ENGLAND

来源：

POLYHEDRON | 1995年 / 14卷 / 20-21期

关键词：

D O I：

10.1016/0277-5387(95)00004-C

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of the compound [{Os(eta(6)-C16H16)Cl-2}(2)] is described. The reactions of the compounds [{M(eta(6)-C16H16)Cl-2}(2)] (M = Ru, Os) with tertiary phosphines are investigated inpolar and non-polar solvents. Neutral compounds [M(eta(6)-C16H16)Cl-2(PR(3))] and cationic complexes [M(eta(6)-C16H16)Cl(PR(3))(2)](+)X(-) (X = PF6, BPh(4)) are obtained, respectively. The crystal structure of a representative compound [Ru(eta(6)-C16H16)Cl-2(PPh(3))] has been determined and the structure is compared with that of the simpler analogue [Ru(eta(6)-C6H6)Cl-2(PPh(3))].

引用

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页码：3147 / 3156

页数：10

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