THE REACTIONS OF [RU(ETA-6-ARENE)CL2]2 COMPOUNDS WITH A SERIES OF AMINOPYRIDINE LIGANDS - X-RAY CRYSTAL-STRUCTURES OF [RU(ETA-6-1,4-MEC6H4CHME2)CL2(NC5H4NH2)] AND [RU(ETA-6-C16H16)CL2(NC5H4NH2)]

被引：22

作者：

ARONSON, R ^{[1
]}

ELSEGOOD, MRJ ^{[1
]}

STEED, JW ^{[1
]}

TOCHER, DA ^{[1
]}

机构：

[1] UNIV LONDON UNIV COLL,DEPT CHEM,20 GORDON ST,LONDON WC1H 0AJ,ENGLAND

来源：

POLYHEDRON | 1991年 / 10卷 / 15期

关键词：

D O I：

10.1016/S0277-5387(00)83792-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of the dimers [Ru(eta-6-arene)Cl2]2 (arene = C6H6, 1,4-MeC6H4CHMe2, [2(2)](1,4)C16H16) with a range of aminopyridine ligands have been investigated. These ligands can potentially coordinate to a single metal centre in a monodentate fashion through either pyridyl or amino nitrogen atoms, can chelate a single metal centre, or can bridge across two metal ions. Spectroscopic data collected on 12 compounds is exclusively consistent with monodentate coordination via the pyridyl nitrogen atoms. This mode of coordination has been conclusively established by X-ray structure determinations of the compounds [Ru(eta-6-1,4-MeC6H4CHMe2)Cl2(NC5H4NH2)] and Ru(eta-6-C16H16) Cl2(NC5H4NH2)].

引用

页码：1727 / 1732

页数：6

共 22 条

[1] SYNTHESIS OF TRIPLE HALIDE-BRIDGED ARENE COMPLEXES OF RUTHENIUM(II) AND OSMIUM(II) [J].

ARTHUR, T ;

STEPHENSON, TA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 208 (03) :369-387

[2] DIVALENT RUTHENIUM COMPLEXES CONTAINING NON-PLANAR HEXAHAPTO-BENZENE [J].

BENNETT, MA ;

SMITH, AK ;

ROBERTSO.GB .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 43 (02) :C41-&

[3] SIMPLE PREPARATION OF BIS-ARENE-RUTHENIUM CATIONIC COMPLEXES, INCLUDING THOSE CONTAINING DIFFERENT ARENES [J].

BENNETT, MA ;

MATHESON, TW .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 175 (01) :87-93

[4]

BENNETT MA, 1982, COMPREHENSIVE ORGANO, V4, pCH32

[5] CYCLOMETALLATION REACTIONS OF 6-PHENYL-2,2'-BIPYRIDINE - A POTENTIAL C,N,N-DONOR ANALOG OF 2,2'-6',2''-TERPYRIDINE - CRYSTAL AND MOLECULAR-STRUCTURE OF DICHLOROBIS(6-PHENYL-2,2'-BIPYRIDINE)RUTHENIUM(II) [J].

CONSTABLE, EC ;

HENNEY, RPG ;

LEESE, TA ;

TOCHER, DA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (02) :443-449

[6] A CONVENIENT PREPARATION OF 2,2'-6',2''-6'',2'''-QUATERPYRIDINE - THE CRYSTAL AND MOLECULAR-STRUCTURES OF 2,2'-6',2''-6'',2'''-QUATERPYRIDINE AND BIS(ACETONITRILE)-(2,2'-6',2''-6'',2'''-QUATERPYRIDINE)NICKEL(II) HEXAFLUOROPHOSPHATE ACETONITRILE(1/1) [J].

CONSTABLE, EC ;

ELDER, SM ;

HEALY, J ;

TOCHER, DA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (05) :1669-1674

[7] THE SYNTHESIS OF NEW PARACYCLOPHANE COMPLEXES OF RUTHENIUM(II) - CRYSTAL-STRUCTURE OF [RU(ETA-6-C16H16)CL(C5H5N)2][PF6] [J].

ELSEGOOD, MRJ ;

TOCHER, DA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 356 (01) :C29-C31

[8] STUDIES ON TRANSITION-METAL PARACYCLOPHANE COMPOUNDS - SYNTHESIS AND CRYSTAL-STRUCTURE OF [OS(ETA-6-C6H6)(ETA-6-[22](1,4)-C16H16)][BF4]2 - SYNTHESIS AND NMR CHARACTERIZATION OF THE TRINUCLEAR HETEROMETALLIC COMPLEX [(ETA-6-C6H6)OS(ETA-6,ETA-6-[22](1,4)C16H16)RU(ETA-6,ETA-6-[22](1,4)C16H16)OS(ETA-6-C6H6)][BF4]6 [J].

ELSEGOOD, MRJ ;

TOCHER, DA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 391 (02) :239-245

[9] THE SYNTHESIS OF NEW BINUCLEAR PARACYCLOPHANE COMPLEXES OF RUTHENIUM(II) - CRYSTAL-STRUCTURE OF [RU2(ETA-6-C16H16)2(OET)3][PF6] [J].

ELSEGOOD, MRJ ;

TOCHER, DA .

INORGANICA CHIMICA ACTA, 1989, 161 (02) :147-149

[10]

Gould R.O., 1978, CRYST STRUCT COMMUN, V7, P27

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