THE MICROSCOPIC STRUCTURE OF BULK AMORPHOUS RED PHOSPHORUS - A RAMAN-SCATTERING INVESTIGATION

被引：66

作者：

OLEGO, DJ ^{[1
]}

BAUMANN, JA ^{[1
]}

KUCK, MA ^{[1
]}

SCHACHTER, R ^{[1
]}

MICHEL, CG ^{[1
]}

RACCAH, PM ^{[1
]}

机构：

[1] UNIV ILLINOIS,DEPT PHYS,CHICAGO,IL 60680

来源：

SOLID STATE COMMUNICATIONS | 1984年 / 52卷 / 03期

关键词：

RAMAN SCATTERING;

D O I：

10.1016/0038-1098(84)90833-0

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

The microscopic structure of bulk amorphous red P has been investigated by Raman scattering. It is concluded that the phosphorus tubes of pentagonal cross-section present in Hittorf's P and KP//1//5 are the structural units of the amorphous red P network. Intratube and intertube correlations are responsible for intermediate range order effects. The Raman data indicate that a continuous transition from the crystalline to the amorphous state takes place for P.

引用

页码：311 / 314

页数：4