ANALYTICAL SOLUTIONS FOR SPIN 7-2 LINE-INTENSITIES IN SOLID-STATE NMR

被引：19

作者：

AGEEV, SZ

SANCTUARY, BC

机构：

[1] Department of Chemistry, McGill University, Montreal, QC

来源：

MOLECULAR PHYSICS | 1995年 / 84卷 / 05期

关键词：

D O I：

10.1080/00268979500100591

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Developments in computer algebra have prompted us to reconsider earlier, intractable problems. Here the density matrix of spin 7/2 subject to the first order quadrupolar interaction and excited by a RF pulse is calculated ignoring rapidly oscillating terms. The results are studied for a variety of conditions which scale as the ratio of the quadrupolar coupling constant to the RF pulse amplitude. The line intensities of the central and satellite transition are also investigated.

引用

页码：835 / 844

页数：10