LITHIUM-ION-CATALYZED EPOXIDATION BY TRIPLET DIOXYGEN - AN ABINITIO STUDY

被引：13

作者：

HOFMANN, H ^{[1
]}

CLARK, T ^{[1
]}

机构：

[1] UNIV ERLANGEN NURNBERG, INST ORGAN CHEM, HENKESTR 42, W-8520 ERLANGEN, GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1990年 / 29卷 / 06期

关键词：

D O I：

10.1002/anie.199006481

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Epoxidation is exothermic with −19.3 kcalmol−1 [Eq. (b)] instead of endothermic with +27.7 kcal mol−1 [Eq. (a)] when carried out in the presence of Li⊕. This emerged from demanding ab‐initio calculations for this model system. Since Li⊕‐catalysis is largely a result of an electrostatic effect, other metal ions should also be able to act as catalysts for epoxidation. (Formula Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：648 / 650

页数：3

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