FLAVONOID COMPOUNDS IN ROOTS OF SOPHORA-TETRAPTERA

被引:21
作者
IINUMA, M
OHYAMA, M
KAWASAKA, Y
TANAKA, T
机构
[1] Department of Pharmacognosy, Gifu Pharmaceutical University, Gifu, 502
关键词
SOPHORA TETRAPTERA; LEGUMINOSAE; ROOTS; FLAVONOIDS; ISOFLAVANONE; PTEROCARPAN; TETRAPTEROL;
D O I
10.1016/0031-9422(95)91511-X
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Two novel flavonoid compounds, an isoflavanone, tetrapterol A, and a pterocarpan, tetrapterol B, and three new isoflavanones, tetrapterols C-E, were isolated from the roots of Sophora tetraptera, in addition to eight known phen;olic compounds (kenusanone A, lespedeol B, euchenone a,, lonchocarpol A, cajanone, (-)-maackiain, isoneorautenol and pentacosanyl caffeate). The two novel compounds had a common characteristic partial structure which is derived from a geranyl group which forms a new aromatic ring after cyclization with a hydroxyl group located at a side ring in a flavonoid framework and dehydrogenation. The new isoflavanones had a geranyl or an isoprenyl group on their A or B ring. The structures were determined by analysis of spectral data, in particular, 2D-NMR.
引用
收藏
页码:667 / 672
页数:6
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