STEREOSELECTIVE REDUCTION OF ALPHA,BETA-EPOXY KETONES INTO ERYTHRO-ALPHA,BETA-EPOXY ALCOHOLS WITH SODIUM-BOROHYDRIDE IN THE PRESENCE OF CALCIUM-CHLORIDE

被引：29

作者：

FUJII, H ^{[1
]}

OSHIMA, K ^{[1
]}

UTIMOTO, K ^{[1
]}

机构：

[1] KYOTO UNIV, FAC ENGN, DEPT IND CHEM, SAKYO KU, KYOTO 60601, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 06期

关键词：

D O I：

10.1246/cl.1992.967

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

erythro-alpha,beta-Epoxy alcohols were prepared with high stereoselectivity by sodium borohydride reduction of the corresponding alpha,beta-epoxy ketones in the presence of calcium chloride or manganese(II) chloride regardless of the substituents on the epoxide ring.

引用

页码：967 / 970

页数：4

共 5 条

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[3] HIGHLY STEREOSELECTIVE SYNTHESIS OF ERYTHRO-ALPHA, BETA-EPOXY ALCOHOLS BY THE REDUCTION OF ALPHA, BETA-EPOXY KETONES WITH ZINC BOROHYDRIDE [J].

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[5]

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