POROUS SURFACTANTS FROM CONE CONFORMERS OF CALIX[5]ARENES

被引：19

作者：

DEDEK, P

JANOUT, V

REGEN, SL

机构：

[1] LEHIGH UNIV,DEPT CHEM,BETHLEHEM,PA 18015

[2] LEHIGH UNIV,ZETTLEMAYER CTR SURFACE STUDIES,BETHLEHEM,PA 18015

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 24期

关键词：

D O I：

10.1021/jo00076a009

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This paper describes the synthesis and monolayer properties of two porous surfactants derived from the calix[5]arene framework that exist as stable cone conformers [i.e., 5,11,17,23,29-pentaformyl-31,32,33,34,35-pentakis(n-octyloxy)calix[5]arene (1a) and an N,N-dimethylthioamide derivative 2a] plus calix[4]arene and calix[6]arene analogs. The introduction of 1a, in and of itself, represents a significant advance in the calixarene area because it provides access to a wide-cavity calixarene that is amenable for further modification at its wider rim.

引用

页码：6553 / 6555

页数：3

共 15 条

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