ASYMMETRICAL COMPLEXATION AND SIMULTANEOUS ELECTROCHEMICAL RECOGNITION OF 2 DIFFERENT GROUP 2 METAL-CATIONS BY A 1,1'-FERROCENE-BIS(METHYLENE AZA-18-CROWN-6) RECEPTOR

被引:14
作者
CHEN, Z [1 ]
PILGRIM, AJ [1 ]
BEER, PD [1 ]
机构
[1] UNIV OXFORD,INORGAN CHEM LAB,OXFORD OX1 3QR,ENGLAND
来源
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1995年 / 91卷 / 23期
关键词
D O I
10.1039/ft9959104331
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Voltammetric (CV, SWV) and fast atom bombardment mass spectrometric evidence demonstrates for the first time that a 1,1'-ferrocene-bis(methylene aza-18-crown-6) receptor (L) is capable of asymmetrically complexing and electrochemically recognising two different Group 2 metal cations (Ba2+, Mg2+) simultaneously in acetonitrile solution.
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页码:4331 / 4333
页数:3
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