PALLADIUM CATALYZED CASCADE CYCLOADDITION REACTIONS - GENERAL CONCEPTS AND ILLUSTRATIVE EXAMPLES

被引：62

作者：

GRIGG, R ^{[1
]}

KENNEWELL, P ^{[1
]}

TEASDALE, A ^{[1
]}

SRIDHARAN, V ^{[1
]}

机构：

[1] ROUSSEL SCI INST,SWINDON SN3 5BZ,ENGLAND

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 01期

关键词：

D O I：

10.1016/S0040-4039(00)60081-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A general palladium catalysed cycloaddition strategy is proposed involving initial oxidative - addition of alkyl -, aryl - and vinyl - halides to Pd(0) followed intermolecular carbopalladation and subsequent intramolecular carbopalladation leading to ring formation. Examples of 5 - and 6 - ring formation are given.

引用

页码：153 / 156

页数：4

共 14 条

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[2] PALLADIUM-CATALYZED SYNTHESES OF CONDENSED CYCLOPENTANES - THE CRYSTAL AND MOLECULAR-STRUCTURE OF 3-BENZYLIDENPENTACYCLO[9.2.1.5,8.11,11.02,10.04,9]-PENTADECANE
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[4] ALKYLPALLADIUM(II) SPECIES - REACTIVE INTERMEDIATES IN A BIS-CYCLIZATION ROUTE TO STRAINED POLYFUSED RING-SYSTEMS
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[J]. TETRAHEDRON LETTERS, 1991, 32 (31) : 3855 - 3858
[5] PALLADIUM-CATALYZED POLYCYCLISATION-ANION CAPTURE PROCESSES
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[J]. TETRAHEDRON LETTERS, 1991, 32 (19) : 2121 - 2124
[8] LEE CM, 1990, J AM SOC, P9330
[9] PALLADIUM-CATALYZED POLYCYCLIZATION OF DIENYNES - SURPRISINGLY FACILE FORMATION OF TETRACYCLIC SYSTEMS CONTAINING A 3-MEMBERED RING
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