[WL(NO)(O)(CH3)] - AN UNUSUAL NITROSYLTUNGSTEN COMPLEX

被引：7

作者：

BOHMER, J

WIEGHARDT, K

NUBER, B

机构：

[1] MAX PLANCK INST STRAHLENCHEM,D-45470 MULHEIM,GERMANY

[2] UNIV HEIDELBERG,INST ANORGAN CHEM,W-6900 HEIDELBERG,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 13-14期

关键词：

COMPLEXES WITH NITROGEN LIGANDS; COMPLEXES WITH OXYGEN LIGANDS; HYDROGEN BONDS; TUNGSTEN COMPOUNDS;

D O I：

10.1002/anie.199514351

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A strong π acceptor and a strong π donor—NO and O ligands, respectively—coordinated cis to the same metal atom are present in the complex 1. The NO stretching frequency of the linear WNO unit occurs at extremely low wavenumber (1433 cm−1). The red complex 1 forms by reduction of [WL(CO)2(NO)]+ to [WL(NO)(CO)(Me)] (L = heterocycle) followed by reaction with O2. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1435 / 1437

页数：3

共 21 条

[1] [Anonymous], 1994, ANGEW CHEM, V106, P1556
[2] THE FIRST MONONUCLEAR NITROSYL(OXO)MOLYBDENUM COMPLEX - SIDE-ON BONDED AND MU(3)-BRIDGING NO LIGANDS IN [(MOL(NO)(O)(OH))(2)]NAPF6-CENTER-DOT-H2O
BOHMER, J
HASELHORST, G
WIEGHARDT, K
NUBER, B
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1994, 33 (14) : 1473 - 1476
[3] SPECTROSCOPIC AND THEORETICAL DESCRIPTION OF THE ELECTRONIC-STRUCTURE OF S=3/2 IRON-NITROSYL COMPLEXES AND THEIR RELATION TO O-2 ACTIVATION BY NONHEME TRON ENZYME ACTIVE-SITES
BROWN, CA
PAVLOSKY, MA
WESTRE, TE
ZHANG, Y
HEDMAN, B
HODGSON, KO
SOLOMON, EI
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (02) : 715 - 732
[4] DISPROPORTIONATION OF A NEUTRAL METAL-FORMYL COMPLEX AND SYNTHESIS OF A STABLE HYDROXYMETHYL-METAL COMPOUND
CASEY, CP
ANDREWS, MA
MCALISTER, DR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (12) : 3371 - 3373
[5] RHENIUM FORMYL AND CARBOXY COMPLEXES DERIVED FROM THE (C5H5)RE(CO)2(NO)+ CATION - MODELS FOR THE FISCHER-TROPSCH AND WATER GAS SHIFT REACTIONS
CASEY, CP
ANDREWS, MA
RINZ, JE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (03) : 741 - 743
[6] PRINCIPLES OF STRUCTURE, BONDING, AND REACTIVITY FOR METAL NITROSYL COMPLEXES
ENEMARK, JH
FELTHAM, RD
[J]. COORDINATION CHEMISTRY REVIEWS, 1974, 13 (04) : 339 - 406
[7] SYNTHESIS AND COORDINATION CHEMISTRY OF THE MACROCYCLE 1,4,7-TRIISOPROPYL-1,4,7-TRIAZACYCLONONANE
HASELHORST, G
STOETZEL, S
STRASSBURGER, A
WALZ, W
WIEGHARDT, K
NUBER, B
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (01): : 83 - 90
[8] A MONONUCLEAR, LOW-VALENT, ELECTRON-RICH OSMIUM METHYLENE COMPLEX
HILL, AF
ROPER, WR
WATERS, JM
WRIGHT, AH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (18) : 5939 - 5940
[9] LAING KR, 1968, J CHEM SOC CHEM COMM, P1556
[10] CP'M(NO)R2 - 16-ELECTRON PIANO-STOOL MOLECULES OF MOLYBDENUM AND TUNGSTEN
LEGZDINS, P
VELTHEER, JE
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1993, 26 (02) : 41 - 48

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