VIBRATIONAL-SPECTRA OF DIMETHYL ALUMINUM-HYDRIDE

被引:22
作者
GRADY, AS [1 ]
PUNTAMBEKAR, SG [1 ]
RUSSELL, DK [1 ]
机构
[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,ENGLAND
来源
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1991年 / 47卷 / 01期
关键词
D O I
10.1016/0584-8539(91)80177-K
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
The infrared and Raman spectra of dimethyl aluminium hydride and its partially deuterated isotopomers are reported and assigned. On the basis of variable temperature studies, coupled with isotope shifts and normal coordinate analysis, it is shown that the vapor phase infrared spectrum at room temperature may be interpreted as predominantly that of the dimer, with smaller amounts of trimer.
引用
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页码:47 / 56
页数:10
相关论文
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