METAL-ASSISTED ACTIVATION OF THE C-O BOND OF 2-HYDROXYETHYLMETHACRYLATE - SYNTHESIS AND MOLECULAR-STRUCTURE OF TI-5(OPRI)(9)(MU-OPRI)(MU,ETA(2)-OC2H4O)(MU(3),ETA(2)-OC2H4O)(3)(MU(4),ETA(2)-OC2H4O)

被引：19

作者：

PAJOT, N

PAPIERNIK, R

HUBERTPFALZGRAF, LG

VAISSERMANN, J

PARRAUD, S

机构：

[1] UNIV NICE,CHIM MOLEC LAB,CNRS,URA,F-06108 NICE 2,FRANCE

[2] CHIM MET TRANSIT LAB,CNRS,URA,F-75252 PARIS 05,FRANCE

[3] CEA,CTR ETUD LIMEIL VALENTON,DAM,F-94195 VILLENEUVE ST GEO,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 17期

关键词：

D O I：

10.1039/c39950001817

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ti-5(OPri)9(mu-OPri)(OC2H4O)(5) is formed by the reaction between Ti(OPri)(4) and 2-hydroxyethylmethacrylate in toluene at room temperature; the pentanuclear aggregate is asymmetric with the titanium atoms displaying coordination numbers of five, six and seven.

引用

页码：1817 / 1819

页数：3