SOLID-STATE ORGANOMETALLIC CHEMISTRY OF TRIPODAL (POLYPHOSPHINE)METAL COMPLEXES - C-H ACTIVATION REACTIONS AT COBALT(I) ENCAPSULATED INTO THE TETRAPHOSPHINE P(CH2CH2PPH2)3

被引：48

作者：

BIANCHINI, C

PERUZZINI, M

ZANOBINI, F

机构：

[1] Istltuto per lo Studio delta Stereochimlca, Energetica dei Compostl di Coordinazione, CNR, 50132 Flrenze

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 10期

关键词：

D O I：

10.1021/om00056a002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The solid-vapor reactions of [(PP3)Co(N2)]-BPh4 with HC = HC, H2C = CH2, CH2O, MeCHO, and CO are described (PP3 = P(CH2CH2PPh2)3). The organic molecules either displace N2, forming a 1:1 complex, or undergo C-H bond cleavage at cobalt to give intermediates that may optionally eliminate H-2 or promote hydrogen transfer from metal to coordinated organic ligand.

引用

页码：3415 / 3417

页数：3

共 12 条

[1] RHODIUM COMPLEXES WITH TRIPODAL POLYPHOSPHINES AS EXCELLENT PRECURSORS TO SYSTEMS FOR THE ACTIVATION OF H-H AND C-H BONDS
BIANCHINI, C
MASI, D
MELI, A
PERUZZINI, M
ZANOBINI, F
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (19) : 6411 - 6423
[2] A STABLE ETA-2-H-2 COMPLEX OF COBALT - ROLE OF THE H-H INTERACTION IN HYDROGEN TRANSFER FROM METAL TO ALKENE
BIANCHINI, C
MEALLI, C
MELI, A
PERUZZINI, M
ZANOBINI, F
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (26) : 8725 - 8726
[3] REACTIVITY OF FORMALDEHYDE AND ACETALDEHYDE TOWARD [N(CH2CH2PPH2)3]NI AND [N(CH2CH2PPH2)3]COH
BIANCHINI, C
MELI, A
[J]. ORGANOMETALLICS, 1985, 4 (09) : 1537 - 1542
[4] BIANCHINI C, IN PRESS ORGANOMETAL
[5] PYROLYSIS OF ACETYLENE - A THERMAL SOURCE OF VINYLIDENE
DURAN, RP
AMOREBIETA, VT
COLUSSI, AJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (10) : 3154 - 3155
[6] VINYLIDENE - THE FINAL CHAPTER
GALLO, MM
HAMILTON, TP
SCHAEFER, HF
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (24) : 8714 - 8719
[7] REACTIONS OF TRIPOD LIGAND TRIS(2-DIPHENYLPHOSPHINOETHYL)PHOSPHINE WITH COBALT(II) AND NICKEL(II) SALTS AND SODIUM-BOROHYDRIDE - STRUCTURAL CHARACTERIZATION OF A 5-COORDINATE COBALT(I) HYDRIDE COMPLEX
GHILARDI, CA
MIDOLLINI, S
SACCONI, L
[J]. INORGANIC CHEMISTRY, 1975, 14 (08) : 1790 - 1795
[8] PI/SIGMA EQUILIBRIA IN METAL-COMPLEXES OF ORGANIC CARBONYL-COMPOUNDS - SYNTHESIS AND STRUCTURE OF CHIRAL RHENIUM COMPLEXES [(ETA-5-C5H5)RE(NO)(PPH3)(O = CHAR)]X
MENDEZ, NQ
ARIF, AM
GLADYSZ, JA
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (12): : 1473 - 1474
[9] SOLID-STATE CHEMISTRY OF MOLECULAR-METAL OXIDE CLUSTERS - MULTIPLE, SEQUENTIAL-C-H ACTIVATION PROCESSES IN THE HYDROGENATION OF COORDINATED CYCLOOCTENE - LATTICE MOBILITY OF SMALL ORGANIC-MOLECULES
SIEDLE, AR
NEWMARK, RA
SAHYUN, MRV
LYON, PA
HUNT, SL
SKARJUNE, RP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (22) : 8346 - 8350
[10] SOLID-STATE CHEMISTRY OF MOLECULAR-METAL OXIDE CLUSTERS - REACTIONS OF MICROPOROUS [(PH3P)2IRH2]3PW12O40 WITH SMALL ORGANIC-MOLECULES
SIEDLE, AR
NEWMARK, RA
[J]. ORGANOMETALLICS, 1989, 8 (06) : 1442 - 1450

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