PHASE-SEPARATION IN CARBOXYLATED POLYSULFONE SOLVENT WATER-SYSTEMS

被引:25
作者
LAU, WWY
GUIVER, MD
MATSUURA, T
机构
[1] NATL RES COUNCIL CANADA,INST ENVIRONM CHEM,OTTAWA K1A 0R6,ONTARIO,CANADA
[2] NATL UNIV SINGAPORE,DEPT CHEM ENGN,SINGAPORE 0511,SINGAPORE
关键词
D O I
10.1002/app.1991.070421214
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The cloud point curves for the ternary systems carboxylated polysulfones/solvent/water were determined by a titration method. Membrane-forming solvents used were NMP, DMAc, DMF, DMSO, TMU, and DMPU. Four modified polysulfones containing 0.43, 0.93, 1.38, and 1.93 carboxyl groups per repeat unit were synthesized for this study. Water/solvent theta-compositions and solubility parameters for these polymers were also estimated.
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页码:3215 / 3221
页数:7
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