REPETITIVE SYNTHESIS OF BULKY DENDRIMERS - A REVERSIBLY PHOTOACTIVE DENDRIMER WITH 6 AZOBENZENE SIDE-CHAINS

被引：64

作者：

MEKELBURGER, HB ^{[1
]}

RISSANEN, K ^{[1
]}

VOGTLE, F ^{[1
]}

机构：

[1] UNIV JYVASKYLA,DEPT CHEM,SF-40351 JYVASKYLA,FINLAND

来源：

CHEMISCHE BERICHTE-RECUEIL | 1993年 / 126卷 / 05期

关键词：

AZOBENZENE UNITS; DENDRIMER; DIVERGENT SYNTHESIS; SOLVENT INCLUSION; SUPRAMOLECULAR CHEMISTRY;

D O I：

10.1002/cber.19931260516

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dendrimers with bulky repeating units containing up to 43 benzene rings (in 9) have been obtained by using a repetitive divergent synthetic strategy (three generations). The new functional dendrimer 13 containing six azobenzene units at the periphery was synthesized allowing a reversible switching of the shape and size of the molecule upon irradiation. An X-ray structure analysis of the dendritic molecule 3a shows the inclusion of acetonitrile.

引用

页码：1161 / 1169

页数：9

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