HARDNESS AS A FUNCTION OF POLARIZABILITY IN A REACTION PROFILE

被引：19

作者：

ROY, RK ^{[1
]}

CHANDRA, AK ^{[1
]}

PAL, S ^{[1
]}

机构：

[1] NATL CHEM LAB,DIV PHYS CHEM,POONA 411008,MAHARASHTRA,INDIA

来源：

THEOCHEM-JOURNAL OF MOLECULAR STRUCTURE | 1995年 / 331卷 / 03期

关键词：

D O I：

10.1016/0166-1280(94)03880-T

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this article, for the first time, we have correlated chemical hardness with polarizability when a single bond in a complex polyatomic molecule is distorted. A predominantly linear relation has been observed between the cube root of polarizability and hardness when various types of bonds are distorted. The molecules CH3Cl, CH3F and CH4 are chosen as typical example systems.

引用

页码：261 / 265

页数：5

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