CORRELATION BETWEEN HARDNESS, POLARIZABILITY, AND SIZE OF ATOMS, MOLECULES, AND CLUSTERS

被引:239
作者
GHANTY, TK [1 ]
GHOSH, SK [1 ]
机构
[1] BHABHA ATOM RES CTR,DIV HEAVY WATER,BOMBAY 400085,INDIA
关键词
D O I
10.1021/j100121a015
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Interesting correlations between the hardness, polarizability, and size of different systems like atoms, molecules, metal clusters, and carbon clusters are demonstrated to exist. This provides support for the use of these physical properties for qualitative characterization of the hard soft acid base concept. Some of these correlations might also be useful in predicting hardness or softness or polarizability of a species from its size.
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页码:4951 / 4953
页数:3
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