THE SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF NA3WO3N

被引：25

作者：

ELDER, SH

DISALVO, FJ

PARISE, JB

HRILJAC, JA

RICHARDSON, JW

机构：

[1] CORNELL UNIV,BAKER LAB,DEPT CHEM,ITHACA,NY 14853

[2] SUNY STONY BROOK,INST MINERAL PHYS,STONY BROOK,NY 11794

[3] BROOKHAVEN NATL LAB,DEPT PHYS,UPTON,NY 11973

[4] ARGONNE NATL LAB,INTENSE PULSED NEUTRON SOURCE,ARGONNE,IL 60439

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1994年 / 108卷 / 01期

关键词：

D O I：

10.1006/jssc.1994.1011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report the discovery of a new ternary oxynitride, Na3WO3N. Na3WO3N is synthesized by exposing a eutectic melt consisting of 1 2Na2O : 1Na2WO4 to a flow of ammonia gas at 695°C. The compound crystallizes in the acentric space group Pmn21 with a = 7.2481(3) Å, b = 6.2728(3) Å, and c = 5.6493(2) Å. The structure was determined from synchrotron X-ray powder diffraction data and refined using the Rietveld analysis on neutron powder diffraction data. It is isostructural to the low temperature form of Li3PO4 which can be derived from an ordered wurtzite structure-type with all the atoms having tetrahedral coordination. Alternatively, the structure can be described as being salt-like consisting of isolated (WO3N)-3 tetrahedral polyanions separated by Na+. © 1994 Academic Press, Inc.

引用

页码：73 / 79

页数：7

共 30 条

[21] NON-BONDED INTERACTIONS AND THE CRYSTAL-CHEMISTRY OF TETRAHEDRAL STRUCTURES RELATED TO THE WURTZITE TYPE (B4) [J].