STUDIES ON THE MICROSTRUCTURE OF POLY(PHENYL GLYCIDYL ETHER) USING THE C-13 NUCLEAR-MAGNETIC-RESONANCE TECHNIQUE

被引：35

作者：

RONDA, JC ^{[1
]}

SERRA, A ^{[1
]}

MANTECON, A ^{[1
]}

CADIZ, V ^{[1
]}

机构：

[1] UNIV ROVIRA & VIRGILI,FAC QUIM,DEPT QUIM QUIM ORGAN,E-43005 TARRAGONA,SPAIN

来源：

POLYMER | 1995年 / 36卷 / 03期

关键词：

POLY(PHENYL GLYCIDYL ETHER); NMR SPECTROSCOPY; MICROSTRUCTURE;

D O I：

10.1016/0032-3861(95)91555-L

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Microstructural details of poly(phenyl glycidyl ether) (PPGE) and its optically active form obtained by the aluminium isopropoxide (AIP)/ZnCl2 ionic-coordinative initiator were analysed by nuclear magnetic resonance techniques. In order to assign the soluble fraction signals unmistakably, PPGE samples had to be synthesized using various cationic initiator systems. Several modifications were studied in the AIP/ZnCl2 initiator system (such as the use of various zinc salts and the addition of water) and the tacticity and irregularity contents of the polymers were determined.

引用

页码：471 / 478

页数：8

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