STUDIES ON THE MICROSTRUCTURE OF POLY(PHENYL GLYCIDYL ETHER) USING THE C-13 NUCLEAR-MAGNETIC-RESONANCE TECHNIQUE

被引：35

作者：

RONDA, JC ^{[1
]}

SERRA, A ^{[1
]}

MANTECON, A ^{[1
]}

CADIZ, V ^{[1
]}

机构：

[1] UNIV ROVIRA & VIRGILI,FAC QUIM,DEPT QUIM QUIM ORGAN,E-43005 TARRAGONA,SPAIN

来源：

POLYMER | 1995年 / 36卷 / 03期

关键词：

POLY(PHENYL GLYCIDYL ETHER); NMR SPECTROSCOPY; MICROSTRUCTURE;

D O I：

10.1016/0032-3861(95)91555-L

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Microstructural details of poly(phenyl glycidyl ether) (PPGE) and its optically active form obtained by the aluminium isopropoxide (AIP)/ZnCl2 ionic-coordinative initiator were analysed by nuclear magnetic resonance techniques. In order to assign the soluble fraction signals unmistakably, PPGE samples had to be synthesized using various cationic initiator systems. Several modifications were studied in the AIP/ZnCl2 initiator system (such as the use of various zinc salts and the addition of water) and the tacticity and irregularity contents of the polymers were determined.

引用

页码：471 / 478

页数：8

共 33 条

[11] POLYMERIZATION OF CHLOROPHENYL GLYCIDYL ETHERS .8. INITIATION OF THE POLYMERIZATION OF PARA-CHLOROPHENYL GLYCIDYL ETHER AND PHENYL GLYCIDYL ETHER BY THE SYSTEM ALUMINUM ISOPROPOXIDE AND ZINC-CHLORIDE (1-1) [J].

JEDLINSKI, Z ;

BERO, M ;

SZEWCZYK, P ;

DWORAK, A .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1981, 19 (03) :749-757

[12]

JEDLINSKI Z, 1979, MAKROMOL CHEM, V180, P949

[13]

JEDLINSKI Z, 1985, ACS SYM SER, V286, P205

[14]

KUSHCH PP, 1979, VYSOKOMOL SOEDIN B, V21, P708

[15] TACTICITY STUDY OF POLYPROPYLENE OXIDE BY C-13 PULSED NMR [J].

LAPEYRE, W ;

CHERADAM.H ;

SPASSKY, N ;

SIGWALT, P .

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1973, 70 (05) :838-842

[16] POLYETHERS .8. ISOTACTIC POLYMERIZATION OF PHENYL GLYCIDYL ETHER [J].

NOSHAY, A ;

PRICE, CC .

JOURNAL OF POLYMER SCIENCE, 1959, 34 (127) :165-170

[17] C-13 NMR-STUDY OF POLY(PROPYLENE OXIDE) AND POLY(1-BUTENE OXIDE) [J].

OGUNI, N ;

SHINOHARA, S ;

LEE, K .

POLYMER JOURNAL, 1979, 11 (10) :755-761

[18] POLYETHERS .5. NEW CATALYSTS FOR THE PREPARATION OF ISOTACTIC POLYPROPYLENE OXIDE [J].

OSGAN, M ;

PRICE, CC .

JOURNAL OF POLYMER SCIENCE, 1959, 34 (127) :153-156

[19]

OSGAN M, 1969, Patent No. 34332445

[20] NMR DETERMINATION OF ENANTIOMERIC PURITY [J].

PARKER, D .

CHEMICAL REVIEWS, 1991, 91 (07) :1441-1457

← 1 2 3 4 →