THE THERMOLYSIS OF POLY(METHYL METHACRYLATE) IN THE PRESENCE OF PHENYLTIN CHLORIDES PH(X)SNCL(4-X) (X=1-3)

被引：12

作者：

CHANDRASIRI, JA

WILKIE, CA

机构：

[1] Department of Chemistry, Marquette University, Milwaukee

来源：

POLYMER DEGRADATION AND STABILITY | 1994年 / 45卷 / 01期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0141-3910(94)90181-3

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The thermal degradation of poly(methyl methacrylate) in the presence of the three phenyltin chlorides, PhSnCl(3), Ph(2)SnCl(2), and Ph(3)SnCl, has been studied and a complete mechanistic interpretation of the reaction is provided. Only a little monomeric methyl methacrylate is produced in the reaction and a significant amount of the starting polymer is converted to a non-volatile, cross-linked tin ester.

引用

收藏

页码：83 / 89

页数：7

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