FLUORINATED ALLYLIC ALCOHOLS AS BUILDING-BLOCKS

被引：28

作者：

ALLMENDINGER, T

ANGST, C

KARFUNKEL, H

机构：

[1] CIBA GEIGY LTD,RES DEPT,CH-4002 BASEL,SWITZERLAND

[2] CIBA GEIGY LTD,INFORMAT TECHNOL,CH-4002 BASEL,SWITZERLAND

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1995年 / 72卷 / 02期

关键词：

FLUORINATED ALLYLIC ALCOHOLS; CARBOCATIONIC REACTIVITY; SYNTHETIC APPROACHES; BUILDING BLOCKS;

D O I：

10.1016/0022-1139(94)00415-C

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A theoretical study on the carbocationic reactivity of 2-fluoroallylic alcohols and derivatives explains some experimental findings. An outline is also given of synthetic approaches towards fluoroallylic amines and more complex carbon skeletons starting with fluoroallylic alcohols.

引用

页码：247 / 253

页数：7

共 66 条

[1] ALLGEIER H, 1987, Patent No. 302826
[2] ALLMENDINGER T, 1991, ACS SYM SER, V456, P186
[3] FLUORINE-CONTAINING ORGANOZINC REAGENTS .6. THE PREPARATION OF ALPHA-TRIFLUOROMETHYL-ALPHA-BETA-UNSATURATED CARBOXYLIC-ACID ESTERS
ALLMENDINGER, T
LANG, RW
[J]. TETRAHEDRON LETTERS, 1991, 32 (03) : 339 - 340
[4] THE HYDROGENATION OF FLUOROOLEFINS
ALLMENDINGER, T
DANDOIS, C
WALLISER, B
[J]. TETRAHEDRON LETTERS, 1991, 32 (24) : 2735 - 2736
[5] FLUOROOLEFIN DIPEPTIDE ISOSTERES .1. THE SYNTHESIS OF GLY-PSI(CF=CH)GLY AND RACEMIC PHE-PSI(CF=CH)GLY
ALLMENDINGER, T
FURET, P
HUNGERBUHLER, E
[J]. TETRAHEDRON LETTERS, 1990, 31 (50) : 7297 - 7300
[6] ETHYL PHENYLSULFINYL FLUOROACETATE, A NEW AND VERSATILE REAGENT FOR THE PREPARATION OF ALPHA-FLUORO-ALPHA,BETA-UNSATURATED CARBOXYLIC-ACID ESTERS
ALLMENDINGER, T
[J]. TETRAHEDRON, 1991, 47 (27) : 4905 - 4914
[7] FLUOROOLEFIN DIPEPTIDE ISOSTERES .2. ENANTIOSELECTIVE SYNTHESIS OF BOTH ANTIPODES OF THE PHE-GLY DIPEPTIDE MIMIC
ALLMENDINGER, T
FELDER, E
HUNGERBUHLER, E
[J]. TETRAHEDRON LETTERS, 1990, 31 (50) : 7301 - 7304
[8] AUER K, 1990, CHIMIA, V44, P120
[9] FLUORINE-CONTAINING ORGANOZINC REAGENTS .2. THE CRYSTAL-STRUCTURE OF (1,1-DICHLORO-2,2,2-TRIFLUOROETHYLZINC CHLORIDE).2(DIMETHYLFORMAMIDE)
BELLUS, D
KLINGERT, B
LANG, RW
RIHS, G
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 339 (1-2) : 17 - 22
[10] SYNTHESES OF ORGANOFLUORINE COMPOUNDS .8. SOLVOLYTIC RING-OPENING OF ALKOXYCHLOROFLUOROCYCLOPROPANES - READY ACCESS TO FLUORINATED ALPHA-BETA-UNSATURATED ALDEHYDES AND KETONES
BESSIERE, Y
SAVARY, DNH
SCHLOSSER, M
[J]. HELVETICA CHIMICA ACTA, 1977, 60 (05) : 1739 - 1746

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