SPECIFIC CONDUCTIVITY OF NACL-ALCL3 AND NACL-ALCL3-AL2S3 MELTS

被引：15

作者：

HJULER, HA ^{[1
]}

BERG, RW ^{[1
]}

ZACHARIASSEN, K ^{[1
]}

BJERRUM, NJ ^{[1
]}

机构：

[1] TECH UNIV DENMARK,CHEM DEPT A,DK-2800 LYNGBY,DENMARK

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1985年 / 30卷 / 02期

关键词：

ALUMINUM AND ALLOYS - ELECTRIC BATTERIES - SALTS - Fused - SODIUM CHLORIDE - SULFUR;

D O I：

10.1021/je00040a022

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The specific conductivity of the pure binary NaCl-AlCl//3 molten salt system was measured in the temperature range 175-400 degree C and with the mole fraction of AlCl//3, X//A//l//C//l//3, ranging from 0. 497 to 0. 600. Sulfur, aluminum metal, and sodium chloride were dissolved in the NaCl-AlCl//3 solvents at ca. 250 degree C, forming polymeric NaAlSCl//2. The specific conductivity of these melts was measured in the range 0 less than X//A//l//2//S//3 less than 0. 08. All conductivity data are given as a polynomial function of temperature and composition. This work is pertinent to molten salt batteries.

引用

页码：203 / 208

页数：6

共 21 条

[1] NEGATIVE OXIDATION-STATES OF THE CHALCOGENS IN MOLTEN-SALTS .1. RAMAN-SPECTROSCOPIC STUDIES ON ALUMINUM CHLOROSULFIDES FORMED IN CHLORIDE AND CHLORALUMINATE MELTS AND SOME RELATED SOLID AND DISSOLVED COMPOUNDS [J].