SPECIFIC CONDUCTIVITY OF NACL-ALCL3 AND NACL-ALCL3-AL2S3 MELTS

被引:15
作者
HJULER, HA [1 ]
BERG, RW [1 ]
ZACHARIASSEN, K [1 ]
BJERRUM, NJ [1 ]
机构
[1] TECH UNIV DENMARK,CHEM DEPT A,DK-2800 LYNGBY,DENMARK
关键词
ALUMINUM AND ALLOYS - ELECTRIC BATTERIES - SALTS - Fused - SODIUM CHLORIDE - SULFUR;
D O I
10.1021/je00040a022
中图分类号
O414.1 [热力学];
学科分类号
摘要
The specific conductivity of the pure binary NaCl-AlCl//3 molten salt system was measured in the temperature range 175-400 degree C and with the mole fraction of AlCl//3, X//A//l//C//l//3, ranging from 0. 497 to 0. 600. Sulfur, aluminum metal, and sodium chloride were dissolved in the NaCl-AlCl//3 solvents at ca. 250 degree C, forming polymeric NaAlSCl//2. The specific conductivity of these melts was measured in the range 0 less than X//A//l//2//S//3 less than 0. 08. All conductivity data are given as a polynomial function of temperature and composition. This work is pertinent to molten salt batteries.
引用
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页码:203 / 208
页数:6
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[21]  
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