A MANGANESE TRIS QUINONE OXIMATO PAIR REVEALING NEW STRUCTURES AND MAGNETIC-PROPERTIES IN MNIII,II CHEMISTRY

被引：28

作者：

BASU, P ^{[1
]}

CHAKRAVORTY, A ^{[1
]}

机构：

[1] INDIAN ASSOC CULTIVAT SCI,DEPT INORGAN CHEM,CALCUTTA 700032,W BENGAL,INDIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 11期

关键词：

D O I：

10.1039/c39920000809

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and isomerism of the first tris-chelated low-spin Mn(III) (1a) and Mn(II) (1b) pair of complexes [MnL3]0,-, of the 4-chloro-o-benzoquinone oxime ligand HL is described; MnL3 has strong preference for mer-geometry but mer- and fac-isomers coexist in solution as well as in the crystal lattice of the [Et4N]+ salt of [MnL3]-.

引用

页码：809 / 810

页数：2