SYNTHESIS, STRUCTURE AND REACTIONS OF A CARBON-DIOXIDE COMPLEX OF IRON(0) CONTAINING 1,2-BIS(DIETHYLPHOSPHINO)ETHANE LIGANDS

被引：36

作者：

KOMIYA, S

AKITA, M

KASUGA, N

HIRANO, M

FUKUOKA, A

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 09期

关键词：

D O I：

10.1039/c39940001115

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of [Fe(N-2)(depe)(2)] with carbon dioxide gives trigonal bipyramidal [Fe(eta(2)-CO2)(depe)(2)], where the coordinated CO2 lies on equatorial plane by an eta(2)-fashion and converts into dimethyl ether and [FeX(CO)(depe)(2)]X (X = I, OTf) on interaction with methyl halide or triflate.

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页码：1115 / 1116

页数：2

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