SYNTHESIS, STRUCTURE AND REACTIONS OF A CARBON-DIOXIDE COMPLEX OF IRON(0) CONTAINING 1,2-BIS(DIETHYLPHOSPHINO)ETHANE LIGANDS

被引：36

作者：

KOMIYA, S

AKITA, M

KASUGA, N

HIRANO, M

FUKUOKA, A

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 09期

关键词：

D O I：

10.1039/c39940001115

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of [Fe(N-2)(depe)(2)] with carbon dioxide gives trigonal bipyramidal [Fe(eta(2)-CO2)(depe)(2)], where the coordinated CO2 lies on equatorial plane by an eta(2)-fashion and converts into dimethyl ether and [FeX(CO)(depe)(2)]X (X = I, OTf) on interaction with methyl halide or triflate.

引用

收藏

页码：1115 / 1116

页数：2

相关论文

共 29 条

[11] CARBON-DIOXIDE COORDINATION CHEMISTRY .5. THE PREPARATION AND STRUCTURE OF RH(ETA-1-CO2)(CL)(DIARS)2 [J].

CALABRESE, JC ;

HERSKOVITZ, T ;

KINNEY, JB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (18) :5914-5915

[12]

DARENSBOURG DJ, 1983, ADV ORGANOMET CHEM, V22, P129

[13] BIFUNCTIONAL ACTIVATION OF CARBON-DIOXIDE - SYNTHESIS AND STRUCTURE OF A REVERSIBLE CO2 CARRIER [J].

FACHINETTI, G ;

FLORIANI, C ;

ZANAZZI, PF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (23) :7405-7407

[14] CARBON-DIOXIDE ACTIVATION AS AN ETA-1-C METALLOCARBOXYLATE - METALLOCARBOXYLATE ESTER DERIVATIVES AS A C1 TEMPLATE IN COORDINATED LIGAND REACTIONS [J].

FORSCHNER, T ;

MENARD, K ;

CUTLER, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (02) :121-122

[15] CARBON-DIOXIDE AND FORMALDEHYDE COORDINATION ON MOLYBDENOCENE TO METAL AND HYDROGEN-BONDS OF THE C-1 MOLECULE IN THE SOLID-STATE [J].

GAMBAROTTA, S ;

FLORIANI, C ;

CHIESIVILLA, A ;

GUASTINI, C .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (10) :2985-2986

[16] METALLOCARBOXYLATE TRIALKYLSILYL ESTERS - A MEANS OF DERIVATIZING THE CARBON-DIOXIDE CONTAINING ETA-1-C METALLOCARBOXYLATES CP(CO)2FECO2-LI+ AND CP(CO)2FECO2-NA+ [J].

GIUSEPPETTI, ME ;

CUTLER, AR .

ORGANOMETALLICS, 1987, 6 (05) :970-973

[17] CARBON-DIOXIDE COORDINATION CHEMISTRY - PREPARATION AND X-RAY CRYSTAL-STRUCTURE OF THE METHOXYCARBONYL COMPLEX [IRCL(CO2ME)-(ME2PCH2CH2PME2)2]FSO FROM A CO ADDUCT [J].

HARLOW, RL ;

KINNEY, JB ;

HERSKOVITZ, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (17) :813-814

[18] CARBON-DIOXIDE COORDINATION CHEMISTRY .3. ADDUCTS OF CO2 WITH IRIDIUM(I) COMPLEXES [J].

HERSKOVITZ, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (07) :2391-2392

[19] CARBON-DIOXIDE COORDINATION CHEMISTRY - STRUCTURE AND SOME CHEMISTRY OF NOVEL CO2 ADDITION PRODUCT IRCL(C-2O-4)(PME-3)-3 [J].

HERSKOVITZ, T ;

GUGGENBERGER, LJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (06) :1615-1616

[20] CARBON-DIOXIDE COORDINATION CHEMISTRY .2. SYNTHESIS AND FTIR STUDY OF CP2TI(CO2)(PME3) [J].

JEGAT, C ;

FOUASSIER, M ;

TRANQUILLE, M ;

MASCETTI, J .

INORGANIC CHEMISTRY, 1991, 30 (07) :1529-1536