SURFACE INTERACTIONS WITH ADSORBED MACROMOLECULES

被引:57
作者
KLEIN, J
机构
[1] Weizmann Inst of Science, Rehovot, Isr, Weizmann Inst of Science, Rehovot, Isr
关键词
POLYMERS; -; Adsorption; SURFACES;
D O I
10.1016/0021-9797(86)90037-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Surface interactions, as revealed by surface force studies between mica sheets in 0. 1-0. 2 M KNO//3 aqueous electrolyte, are critically examined for three different types of macromolecules adsorbed on the surfaces: flexible uncharged polymer, flexible charged polyelectrolyte, and rigid rod protein. Aspects of specific and nonspecific effects, such as surface conformation, the origin of repulsive interactions and the possibility of attractive bridging, as well as the question of equilibrium and reversibility for such adsorbed macromolecular layers, are compared and contrasted.
引用
收藏
页码:305 / 313
页数:9
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