THE MILLIMETER-WAVE AND SUBMILLIMETER-WAVE ROTATIONAL SPECTRUM OF CH3CF3 - OBSERVATION OF THE K=3 SPLITTING

被引：9

作者：

BOCQUET, R

BURIE, J

CHEN, WD

WLODARCZAK, G

DEMAISON, J

机构：

[1] Laboratoire de Spectroscopic Hertzienne, Université de Lille I, 59655 Villeneuve D’Ascq Cedex, URA CNRS 249, Bât

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1994年 / 165卷 / 02期

关键词：

D O I：

10.1006/jmsp.1994.1152

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The ground state rotational spectrum of CH3CF3 was measured from 190 GHz, J = 18, up to 910 GHz, J = 87 and K = 63. These measurements allow us to determine accurate molecular constants, including the three sextic centrifugal distortion constants: H(J), H(JK), and H(KJ). For high-J values, a splitting of the K = 3 lines was observed and the splitting constant h3 could be determined. (C) 1994 Academic Press, Inc.

引用

页码：494 / 499

页数：6

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