PARTIAL WIDTHS AND TIME-DEPENDENT DISSOCIATION DYNAMICS BY THE OPTICAL-POTENTIAL METHOD

被引:17
作者
JOLICARD, G [1 ]
BILLING, GD [1 ]
机构
[1] UNIV COPENHAGEN,HC ORSTED INST,DEPT CHEM,DK-2100 COPENHAGEN,DENMARK
关键词
D O I
10.1063/1.463202
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A procedure to obtain partial widths and branching ratios for half and full collision experiments is developed by using square-integrable wave functions in the framework of the optical potential theory. Stable and precise results are obtained with the two-channel Noro-Taylor model Hamiltonian by calculating the asymptotic quantum flows. This paper discusses the relationships between the long-time limit relaxation induced by the resonance states and the preliminary stage of the dissociation process and shows that, when a simplified scheme is used, parameters as (i) the time at which the flows produced by the resonance are analyzed, (ii) the radial points where this analysis is made, or (iii) the norm of the resonance state, cannot be independently fixed.
引用
收藏
页码:997 / 1003
页数:7
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