SELF-SENSITIZED PHOTOPOLYMERIZATION OF A DIACETYLENE SINGLE-CRYSTAL PTS

被引：3

作者：

BARA, M

SCHOTT, M

SCHWOERER, M

机构：

[1] UNIV BAYREUTH,BAYREUTHER INST MAKROMOLEK FORSCH,W-8580 BAYREUTH,GERMANY

[2] UNIV BAYREUTH,INST PHYS,W-8580 BAYREUTH,GERMANY

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 175卷 / 1-2期

关键词：

D O I：

10.1016/0009-2614(90)85512-B

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The influence of already formed polymer chains on the photopolymerization of the diacetylene crystal pTS has been studied using the holographic method. It is shown that, for wavelengths between 340 and 400 nm, photopolymerization occurs and is faster in more polymerized regions. This sensitized process does not involve polymer excited states, but most probably the monomer triplet. It is a two-quantum process. It is proposed that this "sensitization" is in fact due to the elastic effects of polymer chains into the surrounding monomer matrix. © 1990.

引用

页码：23 / 29

页数：7

共 35 条

[11] STUDIES ON A POLYMERIZABLE CRYSTAL .2. MICROCALORIMETRIC STUDY OF POLYMERIZATION AND POLYMORPHISM OF PARA-TS [J].