RELATIONSHIP BETWEEN PHYSICOCHEMICAL PROPERTIES AND ELECTROOXIDATION BEHAVIOR OF CARBON MATERIALS

被引：68

作者：

GIORDANO, N

ANTONUCCI, PL

PASSALACQUA, E

PINO, L

ARICO, AS

KINOSHITA, K

机构：

[1] UNIV REGGIO CALABRIA,FAC ENGN,I-89100 REGGIO CALABRIA,ITALY

[2] UNIV CALIF BERKELEY,LAWRENCE BERKELEY LAB,DIV APPL SCI,BERKELEY,CA 94720

来源：

ELECTROCHIMICA ACTA | 1991年 / 36卷 / 13期

关键词：

CARBON; ELECTROCHEMICAL OXIDATION; FUEL CELLS; SURFACE OXIDES; INFRARED SPECTROSCOPY; CORROSION;

D O I：

10.1016/0013-4686(91)85075-I

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Various carbon blacks, with widely differing physicochemical properties, were characterized and investigated in corrosion experiments. The oxygen concentration, which was obtained from elemental analysis and infrared analysis, showed a strong correlation to the specific corrosion rate at 1 V in 85% H3PO4 at 170-degrees-C. The corrosion rate increased with an increase in the surface concentration of oxygen. A hypothesis to explain this corrosion behaviour is proposed.

引用

页码：1931 / 1935

页数：5