CATALYTIC-HYDROGENATION OF OLEFINS AND ACETYLENES OVER C60PDN

被引:62
作者
NAGASHIMA, H [1 ]
NAKAOKA, A [1 ]
TAJIMA, S [1 ]
SAITO, Y [1 ]
ITOH, K [1 ]
机构
[1] MIE UNIV, DEPT ELECT & ELECTR ENGN, TSU, MIE 514, JAPAN
关键词
D O I
10.1246/cl.1992.1361
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Organopalladium polymers of buckminsterfullerene, C60Pdn, catalyze hydrogenation of olefins and acetylenes at room temperature under a hydrogen atmosphere. The catalytic activity is mainly dependent on the ratio of C60 to Pd in the polymers. Partial hydrogenation of acetylenes is achieved by adding benzylamine as the cocatalyst.
引用
收藏
页码:1361 / 1364
页数:4
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