C-2 DIAMINE, PSEUDO-C-2 POLY(AMIDE) AND POLY(UREA) AS CHIRAL INDUCTORS IN ASYMMETRIC CATALYSIS

被引:74
作者
GAMEZ, P
DUNJIC, B
FACHE, F
LEMAIRE, M
机构
[1] INST RECH CATALYSE,CATALYSE & SYNTH ORGAN LAB,F-69622 VILLEURBANNE,FRANCE
[2] UNIV LYON 1,ESCIL,F-69622 VILLEURBANNE,FRANCE
关键词
D O I
10.1039/c39940001417
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Chiral C-2 diamine, poly(amide) and poly(urea) act as inductors both in asymmetric hydride transfer reduction of acetophenone and carbon-carbon bond formation with high enantioselectivity of up to 95% enantiomeric excess.
引用
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页码:1417 / 1418
页数:2
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