INTRAMOLECULAR HECK REACTION WITH SUBSTRATES POSSESSING AN ALLYLIC ALCOHOL MOIETY

被引:67
作者
GAUDIN, JM
机构
[1] Firmenich SA, Research Laboratories, CH-1211 Geneva 8
关键词
INTRAMOLECULAR; HECK REACTION; PALLADIUM; CYCLIZATION; ALLYLIC ALCOHOL;
D O I
10.1016/0040-4039(91)80766-Y
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
In this paper we report our investigation on a series of palladium catalysed cyclisations with substrates possessing an allylic alcohol moiety. This methodology provides a good approach to a wide variety of functionalised 5 or 6 membered carbo- or heterocycles. We also demonstrate that it is possible to combine an alkylation and a cyclisation process using the same palladium catalyst system.
引用
收藏
页码:6113 / 6116
页数:4
相关论文
共 34 条