PERCOLATION IN CARBON-BLACK POWDERS

被引:40
作者
EHRBURGERDOLLE, F [1 ]
LAHAYE, J [1 ]
MISONO, S [1 ]
机构
[1] TOKAI CARBON CO,FUJI RES LAB,SHIZUOKA 41014,JAPAN
关键词
CARBON BLACK; PERCOLATION; UNIAXIAL COMPACTION; CONDUCTIVITY; FRACTAL;
D O I
10.1016/0008-6223(94)90123-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The variation of conductivity and pressure transmitted by several carbon black powders is measured as a function of the solid volume fraction during low-speed uniaxial compaction. For all samples made of aggregates, the experimental results of both pressure and conductivity can be fitted with a percolation law. The percolation thresholds are, however, much smaller than the theoretical value phi(*) = 0.15. It is shown that the percolation threshold depends on the mass fractal dimension and on a length R(max) characteristic of the aggregates of a given carbon black.
引用
收藏
页码:1363 / 1368
页数:6
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