GENERATION OF ARYL RADICALS BY THE OXIDATION OF ALPHA-(ARYLAZO)TRIPHENYLMETHANES BY CERIUM(IV) AMMONIUM-NITRATE

被引：7

作者：

ARAI, N ^{[1
]}

NARASAKA, K ^{[1
]}

机构：

[1] UNIV TOKYO, GRAD SCH SCI, DEPT CHEM, BUNKYO KU, TOKYO 113, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1995年 / 68卷 / 06期

关键词：

D O I：

10.1246/bcsj.68.1707

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The one-electron oxidation of alpha-(arylazo)triphenylmethanes by cerium(IV) ammonium nitrate (CAN) generated aryl radicals along with the triphenylmethyl cation. When the reaction was carried out in the presence of appropriate radical-trapping agents, such as arenes and olefins, the corresponding addition products were obtained in moderate yield. The oxidation of the arylazo compounds with CAN was accelerated by the addition of acids.

引用

页码：1707 / 1714

页数：8

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