SYNTHESIS AND STRUCTURE OF BIS(PHENYLTETRAMETHYLCYCLOPENTADIENYL)TITANIUM(III) HYDRIDE - THE FIRST MONOMERIC BIS(CYCLOPENTADIENYL)TITANIUM(III) HYDRIDE

被引：36

作者：

DEWOLF, JM ^{[1
]}

MEETSMA, A ^{[1
]}

TEUBEN, JH ^{[1
]}

机构：

[1] UNIV GRONINGEN,DEPT CHEM,GRONINGEN CTR CATALYSIS & SYNTH,9747 AG GRONINGEN,NETHERLANDS

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 12期

关键词：

D O I：

10.1021/om00012a005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first structurally characterized monomeric bis(cyclopentadienyl)titanium(III) hydride, (C(5)PhMe(4))(2)TiH (4), was synthesized by hydrogenolysis of (C(5)PhMe(4))(2)TiMe (5). Hydride 4 was found to be a monomeric bent sandwich by X-ray diffraction methods, and the pentamethylcyclopentadienyl analogue (C(5)Me(5))(2)TiH (3) is concluded to possess a similar molecular structure by comparison between the spectroscopic and reactivity data for 3 and 4.

引用

页码：5466 / 5468

页数：3

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