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DERIVATIVES OF THIOUREAS AND METAL-COMPLEXES FROM N-THIOCARBAMOYL-BENZIMIDOYL CHLORIDES

被引：7
作者：
BEYER, L
HARTUNG, J
KOHLER, R
机构：
来源：
JOURNAL FUR PRAKTISCHE CHEMIE | 1991年 / 333卷 / 03期
关键词：
D O I：
10.1002/prac.19913330302
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The reactions of nickel(II)-coordinated N-benzoyl-thioureas with acid chlorides are described. With different nucleophiles the title compounds N-thiocarbamoyl-benzimidoyl-chlorides yield N-thiobenzoyl-thioureas, N-thiocarbamoyl-benzimido(thio)esters and N-thiocarbamoyl-benzamidines as chelating agents, respectively. By cyclisation 1,3,5-thiadiazin-2-thiones and 1,2,4-triazoles were obtained. The formation, structure and bonding situation of the ligands and the transition metal complexes are discussed. 1,2,4-Dithiazolium-halometalates, 1,3,5-oxadiazinium salts and selenium analogous are included in this review.
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页码：373 / 388
页数：16
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