学术探索
学术期刊
新闻热点
数据分析
智能评审

DERIVATIVES OF THIOUREAS AND METAL-COMPLEXES FROM N-THIOCARBAMOYL-BENZIMIDOYL CHLORIDES

被引：7
作者：
BEYER, L
HARTUNG, J
KOHLER, R
机构：
来源：
JOURNAL FUR PRAKTISCHE CHEMIE | 1991年 / 333卷 / 03期
关键词：
D O I：
10.1002/prac.19913330302
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The reactions of nickel(II)-coordinated N-benzoyl-thioureas with acid chlorides are described. With different nucleophiles the title compounds N-thiocarbamoyl-benzimidoyl-chlorides yield N-thiobenzoyl-thioureas, N-thiocarbamoyl-benzimido(thio)esters and N-thiocarbamoyl-benzamidines as chelating agents, respectively. By cyclisation 1,3,5-thiadiazin-2-thiones and 1,2,4-triazoles were obtained. The formation, structure and bonding situation of the ligands and the transition metal complexes are discussed. 1,2,4-Dithiazolium-halometalates, 1,3,5-oxadiazinium salts and selenium analogous are included in this review.
引用
收藏
页码：373 / 388
页数：16
相关论文
共 85 条
[11]   N-(AMINO-THIOCARBONYL)-BENZIMIDCHLORIDE [J].
BEYER, L ;
WIDERA, R .
TETRAHEDRON LETTERS, 1982, 23 (18) :1881-1882
[12]  
BEYER L, 1981, Z CHEM, V21, P415
[13]  
BEYER L, 1975, Z CHEM, V15, P197
[14]  
BEYER L, Patent No. 278724
[15]  
BLUM PR, 1976, INORG SYNTH, V16, P225
[16]   STRUCTURE OF N-(DIETHYLAMINOTHIOCARBONYL)BENZAMIDINE [J].
BRAUN, U ;
RICHTER, R ;
SIELER, J ;
BEYER, L ;
LEBAN, I ;
GOLIC, L .
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1988, 44 :355-357
[17]   CRYSTAL AND MOLECULAR-STRUCTURE OF BIS[N-(DIETHYLAMINOTHIOCARBONYL)-BENZAMIDINE]-SILVER(I) NITRATE [J].
BRAUN, U ;
SIELER, J ;
RICHTER, R ;
HETTICH, B ;
SIMON, A .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1988, 557 (02) :134-142
[18]   STRUCTURE OF 2 MODIFICATIONS OF 1,1-DIETHYL-3-THIOBENZOYLTHIOUREA [J].
BRAUN, U ;
RICHTER, R ;
SIELER, J ;
BEYER, L ;
LINDQVIST, O ;
YANOVSKY, AI ;
STRUCHKOV, YT .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1987, 43 :92-95
[19]  
CHAU T, 1989, THESIS U HALLE
[20]   REACTIONS OF TIX4 AND VOCL3 WITH P=S LIGANDS [J].
CUADRADO, I ;
MORAN, M .
TRANSITION METAL CHEMISTRY, 1984, 9 (03) :96-103
123456789