REGIOSELECTIVE ADAMANTYLATION OF N-UNSUBSTITUTED PYRAZOLE DERIVATIVES

被引：14

作者：

CABILDO, P

CLARAMUNT, RM

FORFAR, I

ELGUERO, J

机构：

[1] Univ Nacl Educ Distancia, DEPT QUIM ORGAN & BIOL, E-28040 MADRID, SPAIN

[2] Univ Nacl Educ Distancia, INST QUIM MED, E-28040 MADRID, SPAIN

[3] CSIC, E-28040 MADRID, SPAIN

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 01期

关键词：

D O I：

10.1016/0040-4039(94)88196-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of NH-pyrazoles with 1-bromoadamantane in a high pressure stainless steel autoclave (250 ml, maximum working pressure of 200 atm) gives regioselectively 1-adamantyl or 4-adamantylpyrazoles depending on the temperature.

引用

页码：183 / 184

页数：2

共 14 条

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[2] STRUCTURE OF 1-(1-ADAMANTYL)PYRAZOLES - CRYSTAL GEOMETRY AND C-13 NMR-SPECTROSCOPY
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[10] 1ST SYNTHESIS OF AROMATIC-COMPOUNDS CARRYING 2 1-ADAMANTYLS ON ADJACENT POSITIONS - 3,4-DI-1-ADAMANTYLTHIOPHENE, ORTHO-DI-1-ADAMANTYLBENZENE, AND 4,5-DI-1-ADAMANTYLPYRIDAZINE
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